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Extra resources for Essential Oils Analysis
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The addition of an excess of donor ligands to a solution of [ {Zr(C5H5)}2(p-CH3)(p-CH2)(p-q5:q'CloH8)]+ [BMe(C6F5)3]- in dichloromethane-d2 at - 60 "C affords the cationic ~~s-C~~H~)]+ = adducts [ { Z r ( C ~ H ~ ) } ~ ( C H ~ ) L ( ~ - C H ~ ) ( p - ~ s : [BMe(C6F5)3]-[L PMe3, PMe2Ph, PPh3, THF] obtained as a mixture of syn- and ~ n t i - i s o r n e r s . ~ ~ Substitution of the chloride in Cp*FvTiCl with MR (Fv = C5Me&H2; R = Me, CH2SiMe3, CH2CMe3, CH=CH2, M = Li; R = CHZPh, M = K; R = C3H5, M = MgCI; R = Ph, M = Na) gives Cp*FvTiR.
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