By J.P. Pradier and C.M. Pradier (Eds.)
This e-book derives from a workshop held in Sweden to envision the environmental implications of the dramatic raise in carbon dioxide degrees within the surroundings within the final 50 years and to discover methods of mitigating greenhouse fuel emissions. This multi-disciplinary process makes it crucial studying not just for chemists yet for all engineers, biologists and environmentalists excited by this crucially very important factor
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Extra resources for Carbon Dioxide Chemistry. Environmental Issues
Sawyer, Anal. Chem. 1967, 39, 332. (a)S. Gambarotta, F. Arena, C. F. Zanazzi,. J. Am. Chem. S o c , 1982, 104. 5082. (b)G. Fachinetti, C. F. Zanazzi, J. Am. Chem. Soc. 1978,100, 7405. N. J. H. Chou, C. Creutz, N. Sutin, J. Am. Chem. S o c . 1989, 111. 6591-6601. E. Fujita, C. Creutz, N. J. Szalda, J. Am. Chem. Soc, 1991, U 3 , 343-353. H. M. S. Lewis, J. Am. Chem. Soc. 1990, U 2 , 3420-3426. M. V. H. Busch, Inorg Chem.. 1977, 16, 2206. f C 0 Activation on Transition Metal Surfaces 2 J. -J. Freund * 2 1 ' D E P A R T M E N T O F P H Y S I C A L C H E M I S T R Y , R U H R U N I V E R S I T A T B O C H U M , D-44780 BOCHUM, GERMANY L A B O R A T O R Y O F APPLIED PHYSICS, THE TECHNICAL UNIVERSITY O F D E N M A R K , DK-2800 L Y N G B Y , DENMARK 1.
N. J. H. Chou, C. Creutz, N. Sutin, J. Am. Chem. S o c . 1989, 111. 6591-6601. E. Fujita, C. Creutz, N. J. Szalda, J. Am. Chem. Soc, 1991, U 3 , 343-353. H. M. S. Lewis, J. Am. Chem. Soc. 1990, U 2 , 3420-3426. M. V. H. Busch, Inorg Chem.. 1977, 16, 2206. f C 0 Activation on Transition Metal Surfaces 2 J. -J. Freund * 2 1 ' D E P A R T M E N T O F P H Y S I C A L C H E M I S T R Y , R U H R U N I V E R S I T A T B O C H U M , D-44780 BOCHUM, GERMANY L A B O R A T O R Y O F APPLIED PHYSICS, THE TECHNICAL UNIVERSITY O F D E N M A R K , DK-2800 L Y N G B Y , DENMARK 1.
In the HREEL spectra of a clean Rh(l 11) surface, no loss features were observed following C 0 adsorption at a pressure of 5-10" Pa at 90 K. As thermal desorption measurements (TPD) indicated the presence of adsorbed C 0 (T = 240 K), the negative result in HREELS suggests that C 0 is probably lying down on the surface. Alternatively , we may speculate that the surface coverage of adsorbed C 0 is too low to give detectable loss features in HREEL spectra. 2 1 2 3,4 2 9 2 2 p 2 2 However, the presence of potassium, even at the lowest coverage, exerted a dramatic influence on the adsorption of C 0 and on the HREEL spectra of adsorbed system.